Probing Critical Particle to Polymer Size Ratios for Non-Einstein Behavior in Polymer Nanocomposites

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Enhanced studies of polymer nanocomposites(PNCs)has led to multiple discoveries of PNC’s that exhibit viscosity behavior counter to the classical behavior for filled systems originally defined by Einstein(1). Opposed to the viscosity increase typically observed for the inclusion of rigid, spherical particles into a suspending polymer medium, PNCs have been characterized that clearly show a decrease in the viscosity of the PNC relative to the suspending polymer by incorporating particles with nano-dimensions(2). PNC’s prepared from trimethylsiloxy treated polysilicate nanoparticles of 0.75<Rg<2.1nm with narrow molecular weight PDMS polymers were used to determine critical size ratios for viscosity reduction behavior and to probe the physical phenomena responsible for it.

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Journal: TechConnect Briefs
Volume: 1, Nanotechnology 2014: Graphene, CNTs, Particles, Films & Composites
Published: June 15, 2014
Pages: 265 - 266
Industry sectors: Advanced Materials & Manufacturing | Personal & Home Care, Food & Agriculture
Topics: Advanced Materials for Engineering Applications, Personal & Home Care, Food & Agriculture
ISBN: 978-1-4822-5826-4