Hydrothermal synthesis and Photoluminescent characterization of nanocrystalline BaZrO3

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Uniform well faceted sub-microcrystalline BaZrO3 particles have been obtained by a facile hydrothermal reaction. It is found that both morphology and photoluminescence properties depend on reaction time, complexation surfactant, solvent water to ethanol ratio, as well as the coprecipitation agent. Band gap estimations suggest that blue-green emission intensity, under ultraviolet radiation excitation, depends on the degree of crystal lattice disorder. Such disorder degree on turn depends strongly on the coprecipitating agent and post hydrothermal processing annealing time. Morphology depends on coprecipitant agent molarities and reaction times.

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Journal: TechConnect Briefs
Volume: 1, Nanotechnology 2010: Advanced Materials, CNTs, Particles, Films and Composites
Published: June 21, 2010
Pages: 360 - 363
Industry sector: Advanced Materials & Manufacturing
Topic: Nanoparticle Synthesis & Applications
ISBN: 978-1-4398-3401-5