Nanotech 2010 Vol. 1
Nanotech 2010 Vol. 1
Nanotechnology 2010: Advanced Materials, CNTs, Particles, Films and Composites

Nanoscale Materials Characterization Chapter 1

Dynamics of intermediate to late stage concentration fluctuations during free diffusion experiments

Authors: A. Oprisan, S.A. Oprisan, A. Teklu

Affilation: College of Charleston, United States

Pages: 71 - 74

Keywords: colloidal suspension, nanoparticle, free diffusion, shadowgraph method

Two experiments were performed using shadowgraph visualization technique in order to study the dynamics of concentration fluctuations. Our experimental setup includes an objective attached to the CCD camera to increase the field of view. Using two colloidal suspensions, one with gold and the other with silica colloid, we extracted both the structure factors and the correlation time during the intermediate to late stages of concentration fluctuations during a free diffusion experiment. The temporal evolution of fluctuations is qualitatively investigated using recursive plots and spatial-temporal sections of fluctuating images. Our experiment reveals significant differences between concentration fluctuations induced in silica and gold colloids. The difference is explained not only in terms of the particle size but due to the possible plasmonic interaction between gold nanoparticle and the incident light.

ISBN: 978-1-4398-3401-5
Pages: 976
Hardcopy: $189.95