Nanotech 2009 Vol. 2
Nanotech 2009 Vol. 2
Nanotechnology 2009: Life Sciences, Medicine, Diagnostics, Bio Materials and Composites

Polymer Nanotechnology Chapter 8

Modifying the kinetics of nanoscale diacetylene polymerization for time-temperature indicator applications

Authors: E. Castillo-Martínez, J.H. Reibenspies, L.J. Hall, M. Kozlov, M.C. Biewer, A.C. Harrington, J. Carretero-Gonzalez, D.E. Smith, B. Huffman, T. Prusik, F. Grabiner, R.H. Baughman

Affilation: University of Texas at Dallas, United States

Pages: 461 - 462

Keywords: diacetylenes, time-temperature indicator

The present study describes the crystal structures of selected diacetylene molecules that can be useful for time-temperature indicator applications, and important methods for modifying polymerization kinetics for these applications. Different powder x-ray diffraction patterns, corresponding to different crystal structures, provide clear signatures of higher and lower reactivity phases. The kinetics of polymerization are studied by optical density measurements in the solid state and solvents like trifluoroacetic acid are used to break inter-diacetylene hydrogen bonds, thereby enabling polydiacetylene solubilization and corresponding solution-based spectroscopic studies.

ISBN: 978-1-4398-1783-4
Pages: 590
Hardcopy: $179.95