Nanotech 2008 Vol. 1
Nanotech 2008 Vol. 1
Nanotechnology 2008: Materials, Fabrication, Particles, and Characterization - Technical Proceedings of the 2008 NSTI Nanotechnology Conference and Trade Show, Volume 1

Characterization Chapter 6

Magnetic Properties Of Iron-Filled Multiwalled Carbon Nanotubes

Authors: N. Aguiló-Aguayo, J. García-Céspedes, E. Pascual, E. Bertran

Affilation: IN2UB, Universitat de Barcelona, Spain

Pages: 985 - 989

Keywords: carbon nanotubs, magnetic properties, superparamagnetism, ZFC-FC

Magnetic properties of iron-filled multiwalled carbon nanotubes have been investigated. Hysteretic and temperature dependent magnetic responses reveal a superparamagnetic behaviour at temperatures below 150ºC. The saturation magnetization of the nanowires at 5K is found to be 198 emu/g, slightly different from the expected bulk value 210 emu/g, due to the presence of a small fraction of Fe3C in our samples. Analysis of field-cooled (FC) and the zero-field-cooled (ZFC) curves show a high magnetic anisotropy of the nanowires. Langevin function has been fitted using data at 300K. The average domain size estimated has been corresponding to spherical domains with radius ~5 nm, below the value from TEM observations (radius < 20 nm), suggesting the presence of pseudo-single domains, with multi-domain-like and single-domain-like of radius ~5nm. The temperature dependence of coercivity give us an estimated value of blocking temperature of ~ 402K. Possible uses of these material point to magnetic resonance imaging and other biomedical applications.

ISBN: 978-1-4200-8503-7
Pages: 1,118
Hardcopy: $159.95

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